| 引用本文： |
-
李景林,李斌,黄智,苏涛.分子筛催化合成乳酸异戊酯的研究[J].广西科学,1999,6(3):191-192. [点击复制]
- Li Jinglin,Li Bin,Huang Zhi,Su Tao.Catalytic Synthesis of Isopentyl Lactate on Zeolites[J].Guangxi Sciences,1999,6(3):191-192. [点击复制]
|
|
| 摘要: |
| 用HZSM-5(38)、Mo/HZSM-5(38)、Fe/HZSM-5(38)分子筛催化合成乳酸异戊酯。以Mo/HZSM-5(38)分子筛的催化性能最好。当Mo/HZSM-5(38)分子筛催化剂用量为1g/mol乳酸,乳酸与异戊醇的摩尔比为1:1.2,控制反应温度为150℃时,乳酸异戊酯的产率可达93.8%。催化剂可以回收连续多次使用,在6h内产率仍可保持在93%左右。 |
| 关键词: HZSM-5(38) Mo/HZSM-5(38) Fe/HZSM-5(38) 催化酯化 乳酸异戊酯 |
| DOI： |
| 投稿时间：1999-04-22修订日期：1999-05-18 |
| 基金项目:国家自然科学基金资助(29464011)。 |
|
| Catalytic Synthesis of Isopentyl Lactate on Zeolites |
|
Li Jinglin, Li Bin, Huang Zhi, Su Tao
|
| (College of Chem. & Chemical Engineering, Guangxi University, 10 Xixiangtanglu, Nanning, Guangxi, 530004, China) |
| Abstract: |
| Isopentyl Lactate was catalytic synthesized over HZSM-5(38)、Mo/HZSM-5(38)、Fe/HZSM-5(38) zeolites. The Mo/HZSM-5(38) zeolite had the best catalytic performance.The isopentyl lactate had the yield of 93.8% when amount of Mo/HZSM-5(38) zeolite was 1 g/mol·Lactic acid,acid/alcohol molar ratio of reactant was 1:1.2 and reaction temperature was 150℃.The catalyst is reclaimable and utilizable repeatedly,the yield of the isopentyl lactate could maintain 93% within 6 hours over the reclaimed catalst. |
| Key words: HZSM-5(38) Mo/HZSM-5(38) Fe/HZSM-5(38) catalytic esterification isopentyl lactate |
