摘要: |
合成了稀土1-苯基-3-甲基-4-苯甲酰基吡唑酮-5与18-冠-6的三元固体配合物.由元素分析确定配合物的化学组成为RE(PMBP)3(18C6),其中RE=La~Lu,Y.通过红外光谱、核磁共振、热分析及快原子轰击质谱等方法对配合物进行了表征. |
关键词: 稀土 1-苯基-3-甲基-4-苯甲酰基吡唑酮-5 18-冠-6 配合物 合成 |
DOI: |
投稿时间:1992-01-03 |
基金项目: |
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Synthesis and Properties of the Complexes of Rare Earth 1-Phenyl-3-Methyl-4-Benzoyl -Pyrazolone-5 with 18-Crown-6 Ether |
Liang Fupei
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(Department of Chemistry, Guangxi Normal University, Guilin) |
Abstract: |
New mixed ligsnd complexes of the rare earth 1-phenyl-3-methyl-4-benzoyl-pyrazolone-5 with 18-crown-6 ether have been synthesized.The composition of the complexes is RE (PMBP)3(18C6)(RE=La~Lu,Y).The complexes are Characterized by IR spectra,H'NMR spectra,thermoanalysis and fast atom bombardment mass spectra. |
Key words: rare earth 1-phenyl-3-methyl-4-benzoyl-pyrazolone-5 18-crown-6 ether complex compose |