| 摘要: |
| 合成了稀土1-苯基-3-甲基-4-苯甲酰基吡唑酮-5与18-冠-6的三元固体配合物.由元素分析确定配合物的化学组成为RE(PMBP)3(18C6),其中RE=La~Lu,Y.通过红外光谱、核磁共振、热分析及快原子轰击质谱等方法对配合物进行了表征. |
| 关键词: 稀土 1-苯基-3-甲基-4-苯甲酰基吡唑酮-5 18-冠-6 配合物 合成 |
| DOI: |
| 投稿时间:1992-01-03 |
| 基金项目: |
|
| Synthesis and Properties of the Complexes of Rare Earth 1-Phenyl-3-Methyl-4-Benzoyl -Pyrazolone-5 with 18-Crown-6 Ether |
|
Liang Fupei
|
| (Department of Chemistry, Guangxi Normal University, Guilin) |
| Abstract: |
| New mixed ligsnd complexes of the rare earth 1-phenyl-3-methyl-4-benzoyl-pyrazolone-5 with 18-crown-6 ether have been synthesized.The composition of the complexes is RE (PMBP)3(18C6)(RE=La~Lu,Y).The complexes are Characterized by IR spectra,H'NMR spectra,thermoanalysis and fast atom bombardment mass spectra. |
| Key words: rare earth 1-phenyl-3-methyl-4-benzoyl-pyrazolone-5 18-crown-6 ether complex compose |