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黄慨,杨辉,龙思宇,黎演明,黄日波.CO2-甲醇-甘油合成甘油碳酸酯和碳酸二甲酯展望[J].广西科学院学报,2014,30(2):88-94. [点击复制]
- HUANG Kai,YANG Hui,LONG Si-yu,LI Yan-ming,HUANG Ri-bo.Prospect of Directly Synthesis of Glycerol Carbonate Via Dimethyl Carbonate from Carbon Dioxide, Methanol and Glycerol Reaction System[J].Journal of Guangxi Academy of Sciences,2014,30(2):88-94. [点击复制]
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| CO2-甲醇-甘油合成甘油碳酸酯和碳酸二甲酯展望 |
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黄慨, 杨辉, 龙思宇, 黎演明, 黄日波
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| (广西科学院, 非粮生物质酶解国家重点实验室, 国家非粮生物质能源工程技术研究中心, 广西生物质产业化工程院, 广西生物炼制重点实验室, 广西南宁 530007) |
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| 摘要: |
| 结合二氧化碳-甲醇合成碳酸二甲酯(dimethyl carbonate,DMC)的研究现状和二氧化碳-甘油合成甘油碳酸酯(glycerol carbonate,GC)的研究现状展开论述与讨论分析。形成二氧化碳-甲醇-甘油体系直接合成甘油碳酸酯联产碳酸二甲酯的思路,并探讨其实施的可能途径和潜在的影响因素。 |
| 关键词: 甘油碳酸酯 碳酸二甲酯 二氧化碳 甲醇 甘油 |
| DOI： |
| 投稿时间：2013-10-24修订日期：2013-11-20 |
| 基金项目:广西青年基金项目(2012GXNSFBA053028),广西科学院基金项目(11YJ24SW05),广西科学研究与技术开发项目(桂科攻12118016-4C)资助。 |
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| Prospect of Directly Synthesis of Glycerol Carbonate Via Dimethyl Carbonate from Carbon Dioxide, Methanol and Glycerol Reaction System |
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HUANG Kai, YANG Hui, LONG Si-yu, LI Yan-ming, HUANG Ri-bo
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| (Guangxi Academy of Sciences, State Key Laboratory of Non-food Biomass and Enzyme Technology, National Engineering Research Center for Non-food Biorefinery, Guangxi Biomass Industrialization Engineering Institute, Guangxi Key Laboratory of Biorefinery, Nanning, Guangxi, 530007, China) |
| Abstract: |
| In this paper, the synthesis of dimethyl carbonate from carbon dioxide with methanol and the synthesis of glycerol carbonate from carbon dioxide with glycerol were reviewed. The research progresses of these two processes were discussed and analyzed, and then a directly synthesis of glycerol carbonate via dimethyl carbonate from carbon dioxide, methanol and glycerol reaction system was established. In addition, the possible approach for implementation and the potential influencing factors were described. |
| Key words: glycerol carbonate dimethyl carbonate carbon dioxide methanol glycerol |
