| 引用本文： |
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黄锁义,罗燕,张婧萱.硫酸氢钾催化合成肉桂酸正丙酯[J].广西科学,2008,15(1):55-57. [点击复制]
- HUANG Suo-yi,LUO Yan,ZHANG Jing-xuan.Catalytic Synthesis of Normal Propyl Cinnamylate with Potassium Bisulfare[J].Guangxi Sciences,2008,15(1):55-57. [点击复制]
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| 摘要: |
| 应用硫酸氢钾催化肉桂酸与正丙醇的酯化反应合成肉桂酸正丙酯。硫酸氢钾具有较高的催化活性,可以快速地合成肉桂酸正丙酯,反应的最佳条件为:肉桂酸、正丙醇、硫酸氢钾的摩尔比=1:7.5:0.55,反应时间4h,所得肉桂酸正丙酯的产率为96.1%。该催化剂用量少,易于回收,并且可以重复使用。 |
| 关键词: 肉桂酸正丙酯 肉桂酸 正丙醇 硫酸氢钾 酯化 |
| DOI： |
| 投稿时间：2006-12-22修订日期：2007-01-12 |
| 基金项目:广西壮族自治区教育厅课题(桂教科研[2004]20号);广西百色市科学研究与技术开发第一批立项项目(百科计字[2005]6号)资助 |
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| Catalytic Synthesis of Normal Propyl Cinnamylate with Potassium Bisulfare |
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HUANG Suo-yi, LUO Yan, ZHANG Jing-xuan
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| (Department of Chemistry, Youjiang Medical College for Nationalities, Baise, Guangxi, 533000, China) |
| Abstract: |
| Normal propyl cinnamylate was synthesized by the esterification of normal propyl alcohol with cinnamic acid in the presence of potassium bisulfate monohydrate.The results obtained showed that the potassium bisulfate monohydrate consisted of a fairly high catalytic activity of the esterification reaction.The effects of cinnamic acid and normal propyl alcohol mol ar ratio, the amount of potassium bisulfate monohydrate catalyst applied, and the time of reaction on the yield of normal propyl alcohol and catalysis activity of catalysts reused have been surveyed.In the chemical reaction of the typical condition, the ester yield reached 96.1% (the mol ar ratio of cinnamic acid/normal propyl alcohol/potassium bisulfate=1:7.5:0.55, refluring 4h).Bisulfate monohydrate catalyst can be easily recovered and reused. |
| Key words: normal propyl cinnamylate cinnamie acid normal propyl alcohol potassium bisulfate esterificstion |
